Chemistry Letters p. 561 - 564 (1988)
Update date:2022-08-11
Topics:
LEE, Hyeon Kye
KIM, Kyoung Soo
KIM, Jack C.
KIM, Yong Hae
Acenaphthylene, phenanthrene, and pyrene, which are inert with superoxide itself, were readily oxidized to the corresponding arene oxides by a 2-nitrobenzene sulfonyl-peroxyl radical intermediate (A) generated from 2-nitrobenzenesulfonyl chloride and potassium superoxide in polar aprotic solvents such as acetonitrile, nitromethane, and dimethylformamide under mild conditions.
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