Journal of the American Chemical Society p. 5348 - 5350 (1984)
Update date:2022-08-30
Topics:
Card, Peter J.
Hitz, William D.
1'-Deoxy-1'-fluorosucrose (1) has been synthesized by a sucrose synthetase mediated coupling of 1-deoxy-1-fluoro-D-fructose with UDP-glucose. 1-Deoxy-1-fluoro-D-fructose (2) was prepared from 2,3:4,5-di-O-isopropylidene-D-fructopyranose via tris(dimethylamino)sulfonium difluorotrimethylsilicate (TASF) reaction upon the corresponding trifylate followed by hydrolysis.Fluorosucrose 1 is stable to hydrolysis by invertase and is recognized by the sucrose carrier protein.
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