Journal of Organometallic Chemistry p. 15 - 18 (1994)
Update date:2022-08-16
Topics:
Ohshita, Joji
Masaoka, Yoshiteru
Masaoka, Shin
Ishikawa, Mitsuo
Tachibana, Akitomo
et al.
The reaction of mesitoyl- and (2-methylbenzoyl)tris(trimethylsilyl)silane with 1 equiv. of a silyllithium gave silicon analogs of lithium enolates.Hydrolysis of the lithium silenolates afforded hydrosilanes in high yields.The lithium silenolates can be readily transformed into silenes quantitatively, by treatment with a chlorosilane. Key words: Silicon; Lithium; Unsaturated compounds; Lithium enolates
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