Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy p. 295 - 304 (1983)
Update date:2022-08-10
Topics:
Sbrana, G.
Neto, N.
Muniz-Miranda, M.
Nocentini, M.
The i.r. and Raman spectra of p-bis(dimethyl-hydroxy-silil)tetradeuterobenzene have been obtained and compared with data of the corresponding normal compound.Complete normal mode calculations of both -d0 and -d4 derivatives have been carried out using a set of valence force constants transferred from suitable molecules and refined to account for the observed i.r. and Raman data.Results of a model calculation, in which substituents are considered as point masses, are also discussed in order to provide a convenient starting point to study the chain conformation of a polymer obtained through polycondensation of the investigated molecule.
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