Journal of the American Chemical Society p. 7232 - 7239 (1989)
Update date:2022-08-24
Topics:
Gopalakrishnan, S.
Stone, Michael P.
Harris, Thomas M.
Preparation of a double-stranded aflatoxin B1-oligodeoxynucleotide adduct by direct addition of aflatoxin B1 8,9-epoxide to d(ATCGAT)2 is described.Reaction occurred rapidly at 5 deg C to give a high yield of adduct.The reaction reached a limiting stoichiometry of 1:1 aflatoxin B1 to d(ATCGAT)2.The major product, which exhibited UV absorbance at 360 nm, was identified as 8,9-dihydro-8-(N7-guanyl
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