Inorganic Chemistry
Article
acids was also not observed. Apart from K S O , the use of other
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oxidants (H O , O , t-BuOOH, or KIO ) in the present hydro-
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18b
carboxylations has so far been unsuccessful.
ASSOCIATED CONTENT
Supporting Information
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004, 126, 15802.
7) For recent reviews on the use of CPs in catalysis, see: (a) Ma, L.-
Additional structural representations (Figures S1−S5), differ-
ential thermal analysis plots (Figure S6), and crystallographic
Q.; Abney, C.; Lin, W.-B. Chem. Soc. Rev. 2009, 38, 1248. (b) Lee, J.-
Y.; Farha, O. K.; Roberts, J.; Scheidt, K. A.; Nguyen, S. T.; Hupp, J. T.
Chem. Soc. Rev. 2009, 38, 1450. (c) Farrusseng, D.; Aguado, S.; Pinel,
C. Angew. Chem., Int. Ed. 2009, 48, 7502. (d) Corma, A.; Garcia, H.;
Xamena, F. X. L. Chem. Rev. 2010, 110, 4606. (e) Ranocchiari, M.; van
Bokhoven, J. A. Phys. Chem. Chem. Phys. 2011, 13, 6388.
AUTHOR INFORMATION
A.J.L.P.). Phone: +351 218419207/37. Fax: +351 218464455.
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8) For recent reviews on bioactive metal−organic frameworks, see:
a) McKinlay, A. C.; Morris, R. E.; Horcajada, P.; Ferey, G.; Gref, R.;
Couvreur, P.; Serre, C. Angew. Chem., Int. Ed. 2010, 49, 6260.
b) Horcajada, P.; Gref, R.; Baati, T.; Allan, P. K.; Maurin, G.;
Couvreur, P.; Ferey, G.; Morris, R. E.; Serre, C. Chem. Rev. 2012, 112,
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Pombeiro, A. J. L. Dalton Trans. 2011, 40, 6378. (b) Karabach, Y. Y.;
Guedes da Silva, M. F. C.; Kopylovich, M. N.; Gil-Hernandez, B.;
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1096. (c) Kirillov, A. M.; Kopylovich, M. N.; Kirillova, M. V.;
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The authors declare no competing financial interest.
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ACKNOWLEDGMENTS
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This work was supported by the Foundation for Science and
Technology (FCT) (projects PTDC/QUI-QUI/102150/2008,
PTDC/QUI-QUI/121526/2010, and PEst-OE/QUI/UI0100/
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011), Portugal, as well as its “Science 2007” program. We
Haukka, M.; da Silva, M. F. C. G.; Pombeiro, A. J. L. Angew. Chem., Int.
Ed. 2005, 44, 4345.
(10) (a) Lieberman, R. L.; Rosenzweig, A. C. Nature 2005, 434, 177.
thank Dr. M. C. Oliveira for ESI-MS measurements (IST-node
of the RNEM/FCT).
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b) Chan, S. I.; Wang, V. C.-C.; Lai, J. C.-H.; Yu, S. S.-F.; Chen, P. P.-
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dx.doi.org/10.1021/ic300123d | Inorg. Chem. 2012, 51, 5224−5234