Tetrahedron Letters p. 5059 - 5062 (1986)
Update date:2022-08-24
Topics:
Guo, Zili
Fry, Arthur
In the solvolysis of 1,1,1-trifluoro-2-phenyl-2-propyl-3-14C p-toluenesulfonate there is only a small βC isotope effect, k/βk = 1.008+/-0.002.The result is as expected for a branching SN1/E1 reaction (mostly SN1).This is the first example of such a measurement.
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