Journal of Physical Chemistry p. 575 - 579 (1981)
Update date:2022-08-16
Topics:
Gangwer, T.E.
The heterogeneous mechanism of dehydrogenation for the tetralin/iron catalyst system previously reported is further documented.The temperature dependences of the rate constants are reported.The effective activation energies on these heterogeneous surface were found to be in the -20 to +30 kcal/mol range.The catalytic site populations and temperature dependences were used to determine the binding energy, Rb, of the organic reactants at the catalytic sites.The Eb values were found to be in the 20-40 kcal/mol range.
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