RSC Advances p. 20751 - 20755 (2015)
Update date:2022-08-04
Topics:
Dalmizrak, Di?dem
G?ksu, Haydar
Gültekin, Mehmet Serdar
A novel protocol for the practical and green synthesis of vicinal cis-diols from 10.0 mmol olefins by using 5.0 mmol KMnO4 as oxidant and 30.0 mmol H2O2 as co-oxidant is reported. The presented procedure is easy to carry out and enables the direct transformation of linear and cyclic alkenes to the corresponding vicinal cis-diols. The synthesis of vicinal cis-diols by dihydroxylation of olefins with a KMnO4/H2O2 system was catalyzed by in situ generated MnxOy nanoaggregates. The use of H2O2 as a co-oxidant is the key for the protocol to synthesize vicinal cis-diols in high yields, because it assists the oxidation of MnxOy nanoaggregates, which have an active role in the oxidation reaction medium.
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Doi:10.1016/S0277-5387(02)00852-5
(2002)Doi:10.1016/S0040-4039(02)00668-8
(2002)Doi:10.1021/jo01016a038
(1965)Doi:10.1016/S0040-4039(00)85446-5
(1986)Doi:10.1039/j39700000688
(1970)Doi:10.1021/ja026286k
(2002)