BISISOCYANIDE COMPLEXES OF Zn(II) HALIDES
1757
7.19 s (1H, N=CHN). 13C–{1H} NMR spectrum, δС,
ppm: 18.88, 46.10, 46.35, 46.71, 54.91, 56.39, 127.78,
128.63, 129.50, 149.72, 152.24. Mass spectrum, m/z:
232. 1824 [M + H]+.
4. Bochmann, M., Bwembya, G.C., and Powell, A.K.,
Polyhedron, 1993, vol. 12, p. 2929. doi 10.1016/S0277-
5387(00)80041-8
5. Banh, H., Gemel, C., Seidel, R.W., and Fischer, R.A.,
Chem. Commun., 2015, vol. 51, p. 2170. doi 10.1039/
C4CC08850F
N-Benzyl-N'-(2,6-dimethylphenyl)-N-methylform-
amidine (6d). Yield 0.18 g (92%). 1H NMR spectrum,
δ, ppm: 2.23 s (6Н, CH3), 3.01 s (3Н, CH3), 4.00–5.18
m (2H, CH2), 6.90 t (1Н, p-CH, J = 7.5 Hz), 7.08 d
6. Kulkarni, N.V., Das, A., Jayaratna, N.B., Yousufuddin, M.,
and Dias, H.V.R., Inorg. Chem., 2015, vol. 54, p. 5151.
doi 10.1021/acs.inorgchem.5b00929
(2Н, m-CH, J = 7.5 Hz), 7.22–7.45 m (6H, СНAr
+
7. Banh, H., Dilchert, K., Schulz, C., Gemel, C., Seidel, R.W.,
Gautier, R., Kahlal, S., Saillard, J.-Y., and Fischer, R.A.,
Angew. Chem. Int. Ed., 2016, vol. 55, p. 3285. doi
10.1002/anie.201510762
N=CHN). 13C–{1H} NMR spectrum, δС, ppm: 18.90,
39.87, 57.42, 127.12, 127.43, 128.61, 129.33, 132.17,
133.37, 138.12, 147.27, 151.81. Mass spectrum, m/z:
253.1713 [M + H]+.
8. Lu, W., Hu, H., Li, Y., Ganguly, R., and Kinjo, R.,
J. Am. Chem. Soc., 2016, vol. 138, p. 6650. doi 10.1021/
jacs.6b03432
N-[(4-Methylpiperazin-1-yl)methylene]cyclohexa-
neamine (6g). Yield 0.16 g (95%). 1H NMR spectrum,
δ, ppm: 1.02–1.91 m (10H, CH2), 2.25 s (3Н, CH3),
2.30–2.35 m (4H, CH2), 2.75–2.82 m (1H, CH), 3.19–
3.28 m (4H, CH2), 7.29 s (1H, N=CHN). 13C–{1H}
NMR spectrum, δС, ppm: 24.87, 25.66, 34.08, 44.87,
45.30, 46.94, 55.28, 55.96, 66.72, 154.12. Mass
spectrum, m/z: 210.1984 [M + H]+.
9. Bardsley, K., Hagigeorgiou, M., Lengyel, I., and
Cesare, V., Synth. Commun., 2012, vol. 43, p. 1727. doi
10.1080/00397911.2012.666693
10. Kinzhalov, M.A. and Boyarskii, V.P., Russ. J. Gen.
Chem., 2015, vol. 85, p. 2313. doi 10.1134/
S1070363215100175
11. Melekhova, A.A., Novikov, A.S., Luzyanin, K.V.,
Bokach, N.A., Starova, G.L., Gurzhiy, V.V., and
Kukushkin, V.Y., Inorg. Chim. Acta, 2015, vol. 434,
p. 31. doi 10.1016/j.ica.2015.05.002
N-Benzyl-N-methyl-N'-cyclohexylformamidine
1
(6h). Yield 0.18 g (96%). H NMR spectrum, δ, ppm:
1.13–1.83 m (10H, CH2), 2.78 s (3Н, CH3), 2.95 t.t
(1H, CH, J = 10.5, 4.0 Hz), 4.34 s (2H, CH2), 7.19–
7.37 m (5H, СНAr), 7.57 s (1H, N=CHN). 13C–{1H}
NMR spectrum, δС, ppm: 24.82, 25.73, 34.29, 36.14,
54.76, 64.63, 127.95, 128.10, 128.62, 138.02, 153.21.
Mass spectrum, m/z: 231.1838 [M + H]+.
12. Kinzhalov, M.A., Zolotarev, A.A., and Boyarskiy, V.P.,
J. Struct. Chem., 2016, vol. 57, p. 822. doi 10.1134/
s0022476616040302
13. Kinzhalov, M.A., Boyarskiy, V.P., Luzyanin, K.V.,
Haukka, M., and Kukushkin, V.Yu., Russ. Chem. Bull.,
2013, vol. 62, no. 3, p. 758. doi 10.1007/11172-013-0103-4
14. Kinzhalov, M.A., Luzyanin, K.V., Boyarskaya, I.A.,
ACKNOWLEDGMENTS
Starova, G.L., and Boyarskiy, V.P., J. Mol. Struct.,
2014,
vol.
1068,
p.
222.
doi
10.1016/
The work was supported by Russian Science
Foundation (grant 14-43-00017-P). Physicochemical
studies were performed at the Center for Magnetic
Resonance, Center for X-ray Diffraction Studies, and
Center for Chemical Analysis and Materials Research
(all belong to Saint Petersburg State University).
j.molstruc.2014.04.025
15. Isonitrile Chemistry, Ugi, I., Ed., New York: Academic
Press, 1971, p. 217.
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Silva, M.F.C., Coord. Chem. Rev., 2001, vol. 218, p. 75.
doi 10.1016/S0010-8545(01)00358-7
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