1848
H.H. Monfared et al. / Polyhedron 30 (2011) 1842–1848
Table 5
Oxidation of various substrates with 1/H2O2/CH3CNa.
Entry
1
Substrate
Product(s)
Yield (%)b
73
Conversion (%)
73
Time (h)
5
O
2
1
89
5
O
22
OH
66
O
3
4
42
31
81
77
81
3
5
OH
O
CHO
OH
a
Reaction conditions: catalyst – 1 mg, CH3CN – 3 ml, substrate – 1 mmol, aqueous H2O2 – 3 mmol and temperature 60 1 °C.
Yields are based on the starting substrate.
b
[17] H. Hosseini Monfared, R. Bikas, P. Mayer, Inorg. Chim. Acta 363 (2010) 2574.
[18] T. Hirao, T. Fujii, T. Tanaka, Y. Oshiro, J. Chem. Soc., Perkin Trans. 1 (1994) 3.
[19] H. Hosseini Monfared, Z. Amouei, J. Mol. Catal. A: Chem. 217 (2004) 161.
[20] I.W.C.E. Arends, R.A. Sheldon, Top. Catal. 19 (2002) 133.
1 was established in the oxidation of various hydrocarbons by
using the environmentally benign and clean oxidant H2O2.
[21] A. Altomare, M.C. Burla, M. Camalli, G.L. Cascarano, C. Giacovazzo, A. Guagliardi,
A.G.G. Moliterni, G. Polidori, R. Spagna, J. Appl. Crystallogr. 32 (1999) 115.
[22] G.M. Sheldrick, SHELXS/L-97, Programs for Crystal Structure Determination,
University of Göttingen, Göttingen, Germany, 1997.
[23] DIAMOND (version 3.0) for Windows. Crystal Impact Gbr, Bonn, Germany, 2004.
[24] M.E. Casida, Recent developments and applications in modern density
functional theory, in: J.M. Seminario (Ed.), Theor. Comput. Chem., vol. 4,
Elsevier, Amsterdam, 1996.
[25] C.J. Christopher, Essentials of Computational Chemistry, John Wiley & Sons
Ltd., Chichester, 2002.
Acknowledgements
This work was financially supported by the Zanjan University,
the Faculty of Chemistry and Biochemistry of the Ludwig-Maxim-
ilians-Universität München, and the School of Chemistry.
Appendix A. Supplementary data
CCDC 795784 contains the supplementary crystallographic data
for 1. These data can be obtained free of charge via http://
Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ,
UK; fax: (+44) 1223-336-033; or e-mail: deposit@ccdc.cam.ac.uk.
[26] M.J. Frisch, G.W. Trucks, H.B. Schlegel, G.E. Scuseria, M.A. Robb, J.R. Cheeseman,
J.A. Montgomery, T. Vreven Jr., K.N. Kudin, J.C. Burant, J.M. Millam, S.S. Iyengar,
J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G.A.
Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa,
M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Klene, X. Li, J.E. Knox,
H.P. Hratchian, J.B. Cross, C. Adamo, J. Jaramillo, R. Gomperts, R.E. Stratmann,
O. Yazyev, A.J. Austin, R. Cammi, C. Pomelli, J.W. Ochterski, P.Y.K.
AyalaMorokuma, G.A. Voth, P. Salvador, J.J. Dannenberg, V.G. Zakrzewski, S.
Dapprich, A.D. Daniels, M.C. Strain, O. Farkas, D.K. Malick, A.D. Rabuck, K.
Raghavachari, J.B. Foresman, J.V. Ortiz, Q. Cui, A.G. Baboul, S. Clifford, J.
Cioslowski, B.B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, D.R.L.
Martin, J. Fox, T. Keith, M.A. Al-Laham, C.Y. Peng, A. Nanayakkara, M.
Challacombe, P.M.W. Gill, B. Johnson, W. Chen, M.W. Wong, C. Gonzalez, J.A.
Pople, GAUSSIAN 03, Revision B.03, Gaussian Inc., Pittsburgh, PA, 2003.
[27] A.D. Becke, J. Chem. Phys. 98 (1993) 5648.
References
[1] H.A. Habib, J. Sanchiz, C. Janiak, Inorg. Chim. Acta 362 (2009) 2452.
[2] C. Janiak, J. Chem. Soc., Dalton Trans. (2003) 2781.
[3] S. Jammi, L. Rout, P. Saha, V.K. Akkilagunta, S. Sanyasi, T. Punniyamurthy, Inorg.
Chem. 47 (2008) 5093.
[4] B. Xiao, H. Hou, Y. Fan, J. Mol. Catal. A: Chem. 288 (2008) 42.
[5] F.X. Llabrési Xamena, O. Casanova, R. Galiasso Tailleur, H. Garcia, A. Corma, J.
Catal. 255 (2008) 220.
[28] C. Lee, W. Yang, R.G. Parr, Phys. Rev. B 37 (1988) 785.
[29] W. Plass, Eur. J. Inorg. Chem. (1998) 799.
[6] B. Zhao, P. Cheng, Y. Dai, C. Cheng, D.Z. Liao, S.P. Yan, Z.H. Jiang, G.L. Wang,
Angew. Chem., Int. Ed. 42 (2003) 934.
[7] B. Zhao, L. Yi, P. Cheng, D.Z. Liao, S.P. Yan, Z.H. Jiang, Inorg. Chem. Commun. 7
(2004) 971.
[30] S. Nica, M. Rudolph, H. Girls, W. Plass, Inorg. Chim. Acta 360 (2007) 1743.
[31] B. Mondal, M.G.B. Drew, T. Ghosh, Inorg. Chim. Acta 362 (2009) 3303.
[32] H. Hosseini Monfared, M. Nazari, P. Mayer, M.-A. Kamyabi, A. Erxleben, Z.
Asgari, Z. Naturforsch. 64b (2009) 409.
[8] H. Lin, P.A. Maggard, Inorg. Chem. 47 (2008) 8044.
[9] K. Barthelet, D. Riou, G. Ferey, Solid State Sci. 3 (2001) 203.
[10] Z. Yin-Zhuang, L. Jinli, Inorg. Chem. Commun. 12 (2009) 243.
[11] Y. Qi, E. Wang, J. Li, Y. Li, J. Soild State Chem. 182 (2009) 2640.
[12] G. Mezei, C.M. Zaleski, V.L. Pecoraro, Chem. Rev. 107 (2007) 4933.
[13] B. Kwak, H. Rhee, S. Park, M.S. Lah, Inorg. Chem. 37 (1998) 3599.
[14] O. Pouralimardan, A.-C. Chamayou, C. Janiak, H. Hosseini-Monfared, Inorg.
Chim. Acta 360 (2007) 1599.
[33] M.-L. Tong, X.-M. Chen,B.-L. Ye, L.-N. Ji,Angew. Chem., Int. Ed. Engl. 38 (1999)2237.
[34] H. Hosseini Monfared, M. Vahedpour, M. Mahdavi Yeganeh, M. Ghorbanloo, P.
Mayer, C. Janiak, J. Chem. Soc., Dalton Trans. 40 (2011) 1286.
[35] R. Stratmann, G. Scuseria, M. Frisch, J. Chem. Phys. 109 (1998) 8218.
[36] H. Hosseini Monfared, S. Alavi, R. Bikas, M. Vahedpour, P. Mayer, Polyhedron
29 (2010) 3355.
[37] Y. Marcus, in: J. Rydberg, C. Musikas, G.R. Choppin (Eds.), Principles and
Practices of Solvent Extraction, Marcel Dekker, New York, 1992, p. 23.
[38] A.J. Appleton, S. Evans, J.R. Lindsay, Smith, J. Chem. Soc., Perkin Trans. 2 (1996)
281.
[15] H. Hosseini Monfared, Z. Kalantari, M.-A. Kamyabi, C. Janiak, Z. Anorg. Allg.
Chem. 633 (2007) 1945.
[16] H. Hosseini Monfared, S. Sadighian, M.-A. Kamyabi, P. Mayer, J. Mol. Catal. A:
Chem. 304 (2009) 139.