Journal of Physical Chemistry p. 2249 - 2254 (1981)
Update date:2022-08-17
Topics:
Hatakeyama,Shiro
Bandow, Hiroshi
Okuda, Michio
Akimoto, Hajime
The reactions of peroxymethylene (CH2OO) and singlet methylene with H2O were studied in the gas phase by near-UV photolysis of ketene and diazomethane.Peroxymethylene formed in the reaction of CH2(3B1) + O2 + M----> CH2OO + M was found to react with H2(18)O to produce labeled formic acid: CH2OO + H2(18)O ---> HC(18)OOH + H2O.Singlet Methylene was found to react with H2O to form methanol, CH2(1A1) + H2O ---> CH3OH, competing with the reactiom CH2(1A1) + CH2N2 ---> C2H4 + N2.
View MoreContact:13813902930 025-52714267
Address:20 Fengji Road, Yuhua Economic Development Zone, Nanjing, Jiangsu, P. R. China
Shandong Ailitong New Material Co.,Ltd
Contact:+86-536-3226266
Address:zhongjia village, putong town , qingzhou city,Shandong Province,China
HANGZHOU ZHONGCHANG SCIENTIFIC CO.,LTD
Contact:+86-571-88932183
Address:Hangzhou
HaiNan Periwinkle Pharmaceutical Co.,Ltd.
website:http://www.cchpharm.com/en/index.html
Contact:020-82208978
Address:Gongye road,Wuzhishan city,HaiNan province
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.
Contact:+86-186-02659358
Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China
Doi:10.1021/ic0620586
(2007)Doi:10.1016/j.jorganchem.2016.01.028
(2016)Doi:10.1002/anie.200700949
(2007)Doi:10.1021/ja991077u
(1999)Doi:10.1039/c1ob06012k
(2011)Doi:10.1016/S0040-4039(00)77244-3
(1994)