International Journal of Chemical Kinetics p. 303 - 308 (2006)
Update date:2022-08-17
Topics:
Mohareb, Michael M.
Ghosh, Kallol K.
Palepu, Rama M.
The kinetics of the reaction of methyl 4-nitrobenzenesulfonate + Br - ions has been studied in ethanol amine based (alkyldimethylethanolammonium bromide and alkyldiethylethanolammonium bromide) surfactant solutions. The observed first-order rate constants increase monotonically with surfactant concentration, with hydrophobic chain length and with head group bulk in a manner similar to other quaternary ammonium surfactants. The results were analyzed using the pseudophase model of micellar rate effects in conjunction with a Langmuir form to describe micellar binding of bromide ion. An attempt to estimate activation parameters of the reaction from temperature variance of micellar pseudophase rate constants has also been made.
View MoreHenan Yellow River New Material Technology Co.Ltd.
website:http://www.yellowriverchem.com
Contact:0086-373-7278760
Address:Chengguan Town, Yuanyang County
Jiangyin Tenghua Import&Export Co.,Ltd.
Contact:+86-510-86263875
Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China
Nanyang Tianhua pharmaceutical Co.,Ltd.
Contact:+8618639816203
Address:Longsheng Industrial Park
Tianjin Pharmacn Medical Technology Co.,Ltd.
Contact:86-22-60122566ext.866(English),23359620
Address:Green Industrial Base, 6 Haitaifazhan Sixth Rd., Huayuan Industrial Area, Tianjin, 300384, China
qingdao goldenchem imp and exp co.,ltd.
Contact:532-55579246
Address:no.62 ,haier road laoshan distirct
Doi:10.1016/j.tetlet.2016.11.070
(2016)Doi:10.1002/chem.201500498
(2015)Doi:10.1039/c2cc36791b
(2013)Doi:10.1007/BF00471304
()Doi:10.1021/jo9622845
(1997)Doi:10.1021/jp0126715
(2002)