3
06
KUMAR et al.
nium catalyzed oxidation of inositol by DCICA in 12. S. P. S. Mehta and K. S. Dhami, Himalayan Chem.
Pharm. Bull. 7, 14 (1990).
acetic acid—perchloric acid medium.
1
3. V. L. Devi, G. S. S. Murthy, and K. Sushma, Chem.
When 1 ≪ K [S] i.e., ruthenium(III) exists in
1
Commun. 12, 72 (1986).
mostly in complex form with substrate than in free
1
4. S. Bidyut, M. Kiran Chowdhury, and M. Jayashree, J.
k [Ru(III)] [HOCl]
T
T
form, then Rate =
.
Sol. Chem. 37, 1321 (2008).
+
{
1 + K [H ]}
2
1
5. M. W. Wieczorek, W. O. Karolak, J. Jciechowska,
The above rate law explains unit order in [oxidant]
M. Miko, and M. Witczak, Int. J. Chem. Kinet. 42, 440
(
2010).
and [Ru(III)], zero order in [substrate] and inverse
+
fractional order in [H ] observed in the ruthenium 16. A. Roy and A. K. Das, Ind. J. Chem. A 41, 2468 (2002).
catalyzed oxidation of mannitol and sorbitol by
DCICA in acetic acid—perchloric acid medium.
1
7. S. Sheila, S. Sangeeta, S. Shalini, Parul, and A. Jaiswal,
Bull. Catal. Soc. Ind. 6, 140 (2007).
1
8. E. O. Odebunmi, O. A. Oyetunji, and H. Marufu,
Nigerian J. Sci. 33, 145 (1999).
CONCLUSION
1
9. T. Croguennec, F. Nau, and G. Bruleacute, Int. J.
In the ruthenium(III) catalyzed oxidation of inosi-
tol, D-sorbitol, and D-mannitol by dichloroisocy-
anuric acid in aqueous acetic acid—perchloric acid
media, HOCl is the reactive species which reacts with
the complex (formed between substrate and catalyst)
in a rate determining step to give fragile intermediate
products which decomposes in a fast step to give
monocarboxylic acids (gluconic acid and mannonic
Chem. Kinet. 40, 445 (2008).
20. Y. Lakshman Kumar, R. Venkata Nadh, and P. S. Rad-
hakrishnamurti, Asian J. Chem. 24, 5869 (2012).
21. Y. Lakshman Kumar, R. Venkata Nadh, and P. S. Rad-
hakrishnamurti, Russ. J. Phys. Chem. A 88, 780 (2014).
22. S. M. Desai, N. N. Halligudi, S. T. Nandibewoor,
Trans. Met. Chem. 27, 207 (2002).
acids) in the case of sorbitol and mannitol, but it is a 23. V. H. Rajeshwari, P. S. Anita, T. N. Sharanappa, and
dicarboxylic acid (saccharic acid) in the oxidation of
inositol.
A. C. Shivamurti, Int. J. Chem. Kinet. 42, 440 (2010).
doi: doi 10.1002/kin.20485
24. J. P. Sharma, R. N. P. Singh, A. K. Singh, and
S. Bharat, Tetrahedron. 42, 2739 (1986).
REFERENCES
25. S. Sheila, Trans. Met. Chem. 24, 683 (1999).
1
2
3
4
5
. R. L. Bieleski, in Encyclopaedia of Plant Physiology, 26. N. A. Mohamed Farook, R. Prabaharan, S. Rahini,
New Series, Ed. by F. A. Loewus and W. Tanner,
R. Senthil Kumar, G. Rajamahendran, and B. Gopala
Vol. 13A (Springer, Berlin, 1982), p. 158.
Krishnan, E-J. Chem. 1, 127 (2004).
. U. Anthoni, C. Christophersen, L. Hougaard, and 27. R. Venkata Nadh, B. Syama Sundar, and P. S. Rad-
P. H. Nielsen, Comp. Biochem. Physiol. B 99, 1
1991).
hakrishnamurti, Oxid. Commun. 28, 81 (2005).
(
2
2
3
8. S. Sireesha and R. Venkata Nadh, Bulgar. Chem. Com-
. W. Pigman and D. Horton, Carbohydrates Chemistry
and Biochemistry, 2nd ed. (Academic Press, New York,
mun. 47(1), 13 (2015).
9. E. S. Amis, Solvent Effects on Reaction Rates and Mech-
anisms (Academic, New York, 1966), p. 142.
1972).
. U. Karner, T. Peterbauer, V. Raboy, D. A. Jones,
0. Y. Lakshman Kumar, R. Venkata Nadh, and P. S. Rad-
C. L. Hedley, and A. Richter, J. Exp. Bot. 55, 1981
hakrishnamurti, Bull. Chem. Soc. Ethiop. 29, 1 (2015).
(
2004).
3
1. Y. Lakshman Kumar, R. Venkata Nadh, and P. S. Rad-
. A. R. Alcazar-Roman and S. R. Wente, Chromosoma
17, 1 (2007).
hakrishnamurti, Russ. J. Phys. Chem. A 88, 376 (2015).
1
3
2. S. Mabel, C. Evangelina, M. S. P. Juan, K. Laszlo,
6
. R. H. Michell, Biochem. Soc. Symp. 74, 223 (2007).
. M. Fujita and Y. Jigami, Biochim. Biophys. Acta 1780,
R. Antal, F. S. Luis, and S. Sandra, Polyhedron 26, 169
(2007).
7
410 (2007).
33. A. Anju, S. Gayatri, C. L. Khandelwal, and P. D. Sharma,
Inorg. React. Mech. 4, 233 (2002). doi: doi
8
. X. Tan, L. I. Calderon-Villalobos, M. Sharon,
C. Zheng, C. V. Robinson, M. Estelle, and N. Zheng,
Nature 446, 640 (2007).
10.1080/1028662021000062617
3
3
3
4. A. Rashmi and G. F. Anand, Pharma Chem. 5, 300
2013).
(
9. S. Sheila and S. Parul, Der Chem. Sin. 1 (1), 13 (2010).
5. F. Figel, Spot Tests in Organic Analysis, 5th ed. (Elsevier,
1
0. H. Schiweck, A. Bär, and R. Vogel, Ullmann’s Encyclo-
pedia of Industrial Chemistry, Wiley Online Library
2000).
Amsterdam, 1956), pp. 391, 358.
6. G. H. Jeffery, J. Bassett, J. Mendham and R. C. Den-
ney, Vogel’s Textbook of Quantitative Chemical Analysis,
5th ed. (Longmans Singapore, Singapore, 1996),
pp. 467, 391.
(
11. J. M. H. Stoop and H. Mooibroek, Appl. Environ.
Microbiol. 64, 4689 (1998).
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2016