RSC Advances p. 12816 - 12825 (2013)
Update date:2022-08-18
Topics:
Massah, Ahmad Reza
Kalbasi, Roozbeh Javad
Kaviyani, Somayeh
A manganese Schiff base complex containing salicylaldehyde-poly(vinylamine) /SBA-15 (Mn-SA-PVAm/SBA-15) composite was prepared as a novel heterogeneous catalyst through in situ polymerization of vinylamine within the nano-channels of mesoporous silica SBA-15 without using any organo silica precursors. The catalyst was characterized well by elemental analysis, FT-IR, AAS, DRS UV-Vis, XRD, BET, SEM and TGA techniques. The catalytic activity of the supported metal complex was studied in the selective oxidation of benzyl alcohols using t-butyl hydroperoxide as an oxidant. The effects of reaction temperature, solvent and the amount of catalyst as well as the recyclability of the catalyst were investigated. The Royal Society of Chemistry 2013.
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