Inorganic Chemistry
Article
quinolinolate Complexes: Synthesis, Characterization, Structural, and
Photophysical Properties. Adv. Funct. Mater. 2007, 17, 2365−2376.
(11) Katkova, M. A.; Kurskii, Y. A.; Fukin, G. K.; Averyushkin, A. S.;
Artamonov, A. N.; Vitukhnbovsky, A. G.; Bochkarev, M. N. Efficient
Synthetic Route to Anhydrous Mononuclear Tris(8-quinolinolato)-
lanthanoid Complexes for Organic Light-Emitting Devices. Inorg.
Chim. Acta 2005, 358, 3625−3632.
(28) Llunell, M.; Casanova, D.; Cirera, J.; Alemany, P.; Alvarez, S.,
SHAPE, Version 2.1; Department of Chemistry, University of
Barcelona, 2013.
(29) Shannon, R. D. Revised Effective Ionic-Radii and Systematic
Studies of Interatomic Distances in Halides and Chalcogenides. Acta
Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr. 1976,
32, 751−767.
(30) Perkins, W. G.; Crosby, G. A. Crystal-Field Splitting in Yb3+
Chelates. J. Chem. Phys. 1965, 42, 407−414.
(12) Shavaleev, N. M.; Scopelliti, R.; Gumy, F.; Bunzli, J. C. G.
̈
Modulating the Near-Infrared Luminescence of Neodymium and
Ytterbium Complexes with Tridentate Ligands Based on Benzoxazole-
Substituted 8-Hydroxyquinolines. Inorg. Chem. 2009, 48, 2908−2918.
(31) Asano-Someda, M.; Kaizu, Y. Hot Bands of (F, F*) Emission
from Ytterbium(III) Porphyrins in Solution. J. Photochem. Photobiol.,
A 2001, 139, 161−165.
(13) Shavaleev, N. M.; Scopelliti, R.; Gumy, F.; Bunzli, J. C. G.
̈
(32) Tsvirko, M. P.; Meshkova, S. B.; Venchikov, V. Y.; Topilova, Z.
M.; Bol’shoi, D. V. Determination of Contributions of Various
Molecular Groups to Nonradiative Deactivation of Electronic
Excitation Energy in β-diketonate Complexes of Ytterbium(III).
Opt. Spectrosc. 2001, 90, 669−673.
Near-Infrared Luminescence of Nine-Coordinate Neodymium
Complexes with Benzimidazole-Substituted 8-Hydroxyquinolines.
Inorg. Chem. 2008, 47, 9055−9068.
(14) Wei, H. B.; Yu, G.; Zhao, Z. F.; Liu, Z. W.; Bian, Z. Q.; Huang,
C. H. Constructing Lanthanide [Nd(III), Er(III) and Yb(III)]
Complexes Using a Tridentate N,N,O-ligand for Near-Infrared
Organic Light-Emitting Diodes. Dalton Trans. 2013, 42, 8951−8960.
(15) Bozoklu, G.; Marchal, C.; Pecaut, J.; Imbert, D.; Mazzanti, M.
Structural and Photophysical Properties of Trianionic Nine-
Coordinated Near-IR Emitting 8-Hydroxyquinoline-Based Com-
plexes. Dalton Trans. 2010, 39, 9112−9122.
(33) Meshkova, S. B.; Topilova, Z. M.; Bol’shoi, D. V.; Beltyukova,
S. V.; Tsvirko, M. P.; Venchikov, V. Y. Quantum Efficiency of the
Luminescence of Ytterbium(III) β-diketonate. Acta Phys. Pol., A 1999,
95, 983−990.
(34) McPhillips, T. M.; McPhillips, S. E.; Chiu, H.-J.; Cohen, A. E.;
Deacon, A. M.; Ellis, P. J.; Garman, E.; Gonzalez, A.; Sauter, N. K.;
Phizackerley, R. P.; Soltis, S. M.; Kuhn, P. Blu-Ice and the Distributed
Control System: Software for Data Acquisition and Instrument
Control at Macromolecular Crystallography Beamlines. J. Synchrotron
Radiat. 2002, 9, 401−406.
(16) Shavaleev, N. M.; Eliseeva, S. V.; Scopelliti, R.; Bunzli, J. C. G.
̈
N-Aryl Chromophore Ligands for Bright Europium Luminescence.
Inorg. Chem. 2010, 49, 3927−3936.
(17) Shavaleev, N. M.; Gumy, F.; Scopelliti, R.; Bunzli, J. C. G.
̈
(35) Cowieson, N. P.; Aragao, D.; Clift, M.; Ericsson, D. J.; Gee, C.;
Harrop, S. J.; Mudie, N.; Panjikar, S.; Price, J. R.; Riboldi-Tunnicliffe,
A.; Williamson, R.; Caradoc-Davies, T. Mx1: A Bending-Magnet
Crystallography Beamline Serving Both Chemical and Macro-
molecular Crystallography Communities at the Australian Synchro-
tron. J. Synchrotron Radiat. 2015, 22, 187−190.
Highly Luminescent Homoleptic Europium Chelates. Inorg. Chem.
2009, 48, 5611−5613.
(18) Shavaleev, N. M.; Eliseeva, S. V.; Scopelliti, R.; Bunzli, J. C. G.
̈
Designing Simple Tridentate Ligands for Highly Luminescent
Europium Complexes. Chem. - Eur. J. 2009, 15, 10790−10802.
̈
(19) Shavaleev, N. M.; Scopelliti, R.; Gumy, F.; Bunzli, J. C. G.
(36) Crysalispro; Agilent Technologies Ltd.: Yarton, Oxfordshire,
United Kingdom, 2009−2015.
Benzothiazole- and Benzoxazole-Substituted Pyridine-2-Carboxylates
as Efficient Sensitizers of Europium Luminescence. Inorg. Chem. 2009,
48, 6178−6191.
(37) Kabsch, W. Automatic Processing of Rotation Diffraction Data
from Crystals of Initially Unknown Symmetry and Cell Constants. J.
Appl. Crystallogr. 1993, 26, 795−800.
(20) Shavaleev, N. M.; Eliseeva, S. V.; Scopelliti, R.; Bunzli, J. C. G.
̈
Influence of Symmetry on the Luminescence and Radiative Lifetime
of Nine-Coordinate Europium Complexes. Inorg. Chem. 2015, 54,
9166−9173.
(38) Sheldrick, G. M. A Short History of Shelx. Acta Crystallogr., Sect.
A: Found. Crystallogr. 2008, 64, 112−122.
(39) Sheldrick, G. M. Shelx-2014: Programs for Crystal Structure
(21) Kottas, G. S.; Mehlstaubl, M.; Froehlich, R.; De Cola, L. Highly
Luminescent, Neutral, Nine-Coordinate Lanthanide(III) Complexes.
Eur. J. Inorg. Chem. 2007, 2007, 3465−3468.
̈
̈
Analysis; University of Gottingen: Gottingen, Germany, 2014.
(40) Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A.
K.; Puschmann, H. Olex2: A Complete Structure Solution, Refine-
ment and Analysis Program. J. Appl. Crystallogr. 2009, 42, 339−341.
(41) Macrae, C. F.; Edgington, P. R.; McCabe, P.; Pidcock, E.;
Shields, G. P.; Taylor, R.; Towler, M.; van De Streek, J. Mercury:
Visualization and Analysis of Crystal Structures. J. Appl. Crystallogr.
2006, 39, 453−457.
(22) Botelho, M. B. S.; Galvez-Lopez, M. D.; De Cola, L.;
Albuquerque, R. Q.; de Camargo, A. S. S. Towards the Design of
Highly Luminescent Europium(III) Complexes. Eur. J. Inorg. Chem.
2013, 2013, 5064−5070.
(23) Yamauchi, S.; Hashibe, T.; Murase, M.; Hagiwara, H.;
Matsumoto, N.; Tsuchimoto, M. ’Facial’ and ’Meridional’ Coordina-
tion Geometries and Luminescence Properties of Tris(N-[(imidazol-
4-yl)methylidene]-DL-alaninato)europium(III) and Tris(N-[(imida-
zol-4-yl)methylidene]-DL-phenylalaninato)europium(III). Polyhedron
2013, 49, 105−112.
(24) Andreiadis, E. S.; Imbert, D.; Pecaut, J.; Demadrille, R.;
Mazzanti, M. Self-Assembly of Highly Luminescent Lanthanide
Complexes Promoted by Pyridine-Tetrazolate Ligands. Dalton
Trans. 2012, 41, 1268−1277.
(25) El Ojaimi, M.; Thummel, R. P. Polydentate Analogues of 8-
Hydroxyquinoline and Their Complexes with Ruthenium. Inorg.
Chem. 2011, 50, 10966−10973.
(26) Cao, L. Y.; Lin, Z. K.; Peng, F.; Wang, W. W.; Huang, R. Y.;
Wang, C.; Yan, J. W.; Liang, J.; Zhang, Z. M.; Zhang, T.; Long, L. S.;
Sun, J. L.; Lin, W. B. Self-Supporting Metal-Organic Layers as Single-
Site Solid Catalysts. Angew. Chem., Int. Ed. 2016, 55, 4962−4966.
(27) Ruiz-Martínez, A.; Casanova, D.; Alvarez, S. Polyhedral
Striuctures with an Odd Number of Vertices: Nine-Coordinate
Metal Compounds. Chem. - Eur. J. 2008, 14, 1291−1303.
(42) Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, H. B.;
Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci,
B.; Petersson, G. A.; Nakatsuji, H.; Caricato, M.; Li, X.; Hratchian, H.
P.; Izmaylov, A. F.; Bloino, J.; Zheng, G.; Sonnenberg, J. L.; Hada, M.;
Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.;
Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.;
Montgomery, J. A., Jr.; Peralta, J. E.; Ogliaro, F.; Bearpark, M.;
Heyd, J. J.; Brothers, E.; Kudin, K. N.; Staroverov, V. N.; Keith, T.;
Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A.; Burant, J.
C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Rega, N.; Millam, J. M.;
Klene, M.; Knox, J. E.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo,
J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi,
R.; Pomelli, C.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.;
Zakrzewski, V. G.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.;
Dapprich, S.; Daniels, A. D.; Farkas, O.; Foresman, J. B.; Ortiz, J. V.;
Cioslowski, J.; Fox, D. J. Gaussian 09W, Revision B.01; Gaussian, Inc.:
2010.
(43) Dutra, J. D. L.; Filho, M. A. M.; Rocha, G. B.; Freire, R. O.;
Simas, A. M.; Stewart, J. J. P. Sparkle/PM7 Lanthanide Parameters for
J
Inorg. Chem. XXXX, XXX, XXX−XXX