Tetrahedron p. 8797 - 8810 (1998)
Update date:2022-08-03
Topics:
Makosza, Mieczyslaw
Stalinski, Krzysztof
Tertiary carbanions generated from α-substituted phenylacetonitriles in liquid ammonia add to nitrobenzenes in the para position to form the corresponding σ(H)-adducts which are transformed, depending on the starting nitriles and the reaction conditions, to products of oxidative nucleophilic substitution of hydrogen, ONSH or vicarious nucleophilic substitution, VNS.
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