Journal of Fluorine Chemistry p. 125 - 134 (1993)
Update date:2022-08-11
Topics:
Buerger, Wolfgang
Lunkwitz, Klaus
Model compounds related to the reaction products of perfluooalkenes produced by the electron-beam irradiation of poly(tetrafluoroethylene) with dinucleophilic reactants have been synthesized.Such model compounds, in reaction with diphenols or diamines, give information relating to the mechanism of crosslinking reactions.Results obtained with perfluorohept-1-ene show that terminal perfluoroalkenes react preferentially with dinucleophilic reactants to give unsaturated ether and amine structures.
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(1949)