Journal of the American Chemical Society p. 8231 - 8236 (1989)
Update date:2022-08-16
Topics:
Turos
Audia
Danishefsky
A total synthesis of the Fusarium mycotoxin equisetin, in a manner that establishes its stereochemistry, is described. The key steps involve a lactonic variation of the ester enolate Claisen rearrangement and a novel construction of a 1-acyltetramic acid from an L-N-methylserine derivative and a β-keto ester.
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Doi:10.1021/jp9700793
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