Research on Chemical Intermediates p. 1839 - 1846 (2012)
Update date:2022-08-11
Topics:
Yan, Tingfeng
Hong, Mei
Niu, Lei
Jiang, Feng
Xiao, Guomin
Oxidation of 2-methylnaphthalene (2-MN) with aqueous hydrogen peroxide was conducted in acetic acid. The epoxidation pathway was investigated by increasing the CH3CO3H content and adding manganese(II) naphthenate (MnPc) as catalyst. 2-Methyl-1,4-naphthoquinone was obtained in 75.6% conversion and with 80.0% selectivity under the latter conditions. A probable mechanism in which MnPc catalyzes the oxidation of 2-MN by hydrogen peroxide in acetic acid is proposed. Springer Science+Business Media B.V. 2012.
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