Synthetic Communications p. 1773 - 1782 (1992)
Update date:2022-08-10
Topics:
Tong
Wong
The unique diazafluoranthene alkaloid eupolauridine (1) was synthesized by a three-step routine utilizing as the initial step the thermal rearrangement of the oxime O-crotyl ether 12, which afforded onychine (2). Bracher pyridine synthesis procedure subsequently converted 2 into 1. On the other hand, Friedlander reaction was employed for the synthesis of 3, which is a benzo-annulated derivative of eupolauridine (1).
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