Bulletin of the Chemical Society of Japan p. 1626 - 1630 (1985)
Update date:2022-08-16
Topics:
Sotani, Noriyuki
Yoshida, Noritetsu
Yoshioka, Yukio
Kishimoto, Shozo
Orthorhombic bronze, H0.30MoO3, was decomposed by vacuum heating to MoO2.86 with a rhombic MoO3 structure.The surface area increased slightly with the increase in the rhombic structure in which vacancies were produced.An approximate linear relationship was found between the catalytic activity of 1-butene isomerization and the hydrogen content(x) in the samples which were treated in air at 65 deg C or in vacuo below 220 deg C.On the other hand, the activity above 220 deg C increased with the formation of vacancies.
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