Organometallics
Article
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Figure 5. Molecular structure of 3. Hydrogen atoms are omitted for
clarity. Thermal ellipsoids are drawn at the 30% probability level.
Selected bond length (Å) and angles (deg): Ru−C 1.984(5); C−Ru−
C′ 106.3(3), 111.06(14).
ASSOCIATED CONTENT
* Supporting Information
■
S
Crystallographic data and experimental details, crystal struc-
tures and selected bond lengths and angles, and CIF data. This
material is available free of charge via the Internet at http://
AUTHOR INFORMATION
Corresponding Author
■
(25) Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry, 5th
ed.; Wiley: New York, p 1210.
(26) The biaryl ligand in [{η6-2(2-MeC6H4)MeC6H4}Os(2-
MeC6H4)2L] (L = RNC) is labile. Reaction of [{η6-2(2-MeC6H4)
MeC6H4}Os(2-MeC6H4)2L] with excess L gave cis-[Os(2-
MeC6H4)2L4] (ref 3a).
Notes
The authors declare no competing financial interest.
ACKNOWLEDGMENTS
(27) Miranda, K. M.; Bu, X.; Lorkovic,
1997, 36, 4838.
́
I.; Ford, P. C. Inorg. Chem.
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This work was supported by the Hong Kong Research Grants
Council (Project 602913) and the Hong Kong University of
Science and Technology.
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Addo, G. B. Inorg. Chem. 1996, 35, 1343. (c) Bohle, D. S.; Hung, C.-
H.; Smith, B. D. Inorg. Chem. 1998, 37, 5798.
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dx.doi.org/10.1021/om500707e | Organometallics XXXX, XXX, XXX−XXX