Tetrahedron Letters p. 1195 - 1198 (2000)
Update date:2022-08-10
Topics:
Beraud, Valérie
Gnanou, Yves
Walton, John C.
Maillard, Bernard
A study of the reaction of α,β-unsaturated carbonyl compounds with triethylborane under free radical conditions (Brown's reaction) including spectroscopic analyses (11B NMR, IR, EPR) of products and intermediates indicated that these reactions involve the prior formation of an 'α,β- unsaturated carbonyl compound-organoborane' complex. (C) 2000 Elsevier Science Ltd.
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