Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics p. 287 - 290 (1997)
Update date:2022-08-25
Topics:
Lehmann, Lars
Matejcik, Stefan
Illenberger, Eugen
We report on the SN2 reaction F- + CH3Br→FCH3 + Br- in binary clusters composed of CH3Br and C2F6 in a crossed electron/molecular beam experiment. The reaction is induced by resonance dissociative electron attachment to the C2F6 component where the nucleophile F- is generated at an energy (around 3.8 eV) where CH3Br does not capture electrons to form Br-. The results indicate that the cross section for the SN2 reaction is independent of the total excess energy which can be varied between 1.7 and 5 eV in the present system. VCH Verlagsgesellschaft mbH 1997.
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