Journal of the American Chemical Society
Communication
cage escape of the carbon radical is a key question that remains
challenging to assess. The direct examination of the radical
rebound reaction described here foreshadows further exper-
imental approaches to address these fundamental mechanistic
issues.
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ASSOCIATED CONTENT
Supporting Information
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(9) Draksharapu, A.; Li, Q.; Roelfes, G.; Browne, W. R. Dalton Trans.
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*
S
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X-ray crystallographic data for 1 (CIF)
X-ray crystallographic data for 2 (CIF)
Syntheses and spectroscopy, including Scheme S1,
Figures S1−S19, and Tables S1−S7 (PDF)
(
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AUTHOR INFORMATION
ORCID
Notes
D. P. J. Am. Chem. Soc. 2016, 138, 12791−12802.
(12) Boyle, T. J.; Ottley, L. A. M.; Apblett, C. A.; Stewart, C. A.;
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15) Roelfes, G.; Lubben, M.; Chen, K.; Ho, R. Y. N.; Meetsma, A.;
̈
The authors declare no competing financial interest.
1
(
ACKNOWLEDGMENTS
■
Genseberger, S.; Hermant, R. M.; Hage, R.; Mandal, S. K.; Young, V.
G., Jr.; Zang, Y.; Kooijman, H.; Spek, A. L.; Que, L., Jr.; Feringa, B. L.
Inorg. Chem. 1999, 38, 1929−1936.
The NIH (GM119374 to D.P.G. and G.N.L.J.) is gratefully
acknowledged for financial support. G.N.L.J. further thanks the
University of Otago and the Faculty of Science, University of
Melbourne, for financial support.
(16) (a) Jonas, R. T.; Stack, T. D. P. J. Am. Chem. Soc. 1997, 119,
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566−8567. (b) Chang, K.-C.; Huang, C.-J.; Chang, Y.-H.; Wu, Z.-H.;
Kuo, T.-S.; Hsu, H.-F. Inorg. Chem. 2016, 55, 566−572. (c) Moon, D.;
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