Dyes and Pigments p. 129 - 138 (2016)
Update date:2022-08-11
Topics:
Solanke, Parmeshwar
Achelle, Sylvain
Cabon, Nolwenn
Pytela, Old?ich
Barsella, Alberto
Caro, Bertrand
Robin-le Guen, Fran?oise
Podlesny, Jan
Klikar, Milan
Bure?, Filip
Fifteen new push-pull chromophores based on a proaromatic pyranylidene donor and its chalcogen analogues and various electron acceptor moieties were synthesized in a straightforward manner. These model molecules were designed and prepared to investigate the concept of proaromaticity as a tool to tune the fundamental properties of push-pull systems. All target chromophores with systematically varied structure were further investigated by electrochemistry, absorption spectra, and EFISH experiment in conjunction with DFT calculations. Employing structural variations such as chalcogen/acceptor replacement, extension of the π-system, and the position of substitution along the pyran ring, the HOMO-LUMO gap can be tuned within the range of 2.18 to 1.41?eV. A new and powerful electron withdrawing moiety, combining features of polarizable thiophene and successful indane-1,3-dione acceptor, cyclopenta[c]thiophen-4,6-dione (ThDione) has also been developed.
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Doi:10.1021/acs.joc.6b02811
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