Chemistry Letters p. 327 - 328 (1985)
Update date:2022-08-11
Topics:
Tashiro, Masashi
Kobayashi, Kazumasa
Yamato, Takehiko
Reaction of 8,16-dimethyl<2.2>metacyclophan-1-enes with protonic acids such as 57percent hydroiodic acid and trifluoroacetic acid afforded the corresponding 10b,10c-dihydro-10b,10c-dimethylpyrenes.Similar reaction with 47percent hydrobromic acid and 36percent hydrochloric acid gave surprisingly halogenated 10b,10c-dihydro-10b,10c-dimethylpyrenes.
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