Phytochemistry p. 219 - 223 (1997)
Update date:2022-08-30
Topics:
Belay, Abebaw
Moges, Ghirma
Solomon, Theodros
Johansson, Gillis
The rate constants and reaction order for the conversion of the neurotoxin β-ODAP to α-ODAP have been determined, after off-line thermal treatment, using the recently developed flow injection system for the neurotoxin based on a glutamate oxidase reactor. The effects of the initial concentration of the toxin, temperature and pH on the kinetics and the equilibrium of the endothermic process were examined. The conversion followed a zero order rate law. The reaction rate at pH 7 increased by about two-fold for every 10°temperature rise. The rate at pH 2 was about 60% higher than at pH 7.
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