Tetrahedron p. 1485 - 1492 (2016)
Update date:2022-08-17
Topics:
Fujita, Ken-Ichi
Hattori, Hatsuhiko
We prepared several of a new type of a dendritic ligand with a phosphine core by using tris(4-hydroxyphenyl)phosphine oxide and poly(aryl ether) dendron. In particular, when an amphiphilic dendritic phosphine-palladium complex was used as a catalyst, the aqueous media Suzuki-Miyaura reaction proceeded smoothly to provide the corresponding cross-coupling product at 50 °C. A positive dendritic effect on chemical yields was observed.
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