Inorganic Chemistry
Article
Orthorhombic Mo-V-Sb Oxide Species by Assembly of Pentagonal
ASSOCIATED CONTENT
Supporting Information
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Mo O Polyoxometalate Building Blocks. Angew. Chem., Int. Ed.
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21
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S
2
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009, 48, 3782−3786.
11) Zhan, C.; Cameron, J. M.; Gabb, D.; Boyd, T.; Winter, R. S.;
Vila, L.; Mitchell, S. G.; Glatzel, S.; Breternitz, J.; Gregory, D. H.;
Long, D.; Macdonell, A.; Cronin, L. A Metamorphic Inorganic
Framework That Can Be Switched between Eight Single-Crystalline
States. Nat. Commun. 2017, 8, 14185.
Additional XRD patterns, FTIR spectra, XPS profiles,
SEM images, EDX-mapping images, Rietveld refine-
ments, a TEM image, TPD−MS profiles, N adsorp-
tion−desorption isotherms, CO adsorption isotherms,
catalytic results, a stepwise reaction scheme, the atomic
position of the materials, crystallographic information of
the materials, and catalytic activity of the reported
(12) Mitchell, S. G.; Streb, C.; Miras, H. N.; Boyd, T.; Long, D.-L.;
2
Cronin, L. Face-Directed Self-Assembly of an Electronically Active
Archimedean Polyoxometalate Architecture. Nat. Chem. 2010, 2,
2
3
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08−312.
13) Zhang, Z.; Sadakane, M.; Murayama, T.; Izumi, S.; Yasuda, N.;
Sakaguchi, N.; Ueda, W. Tetrahedral Connection of ε-Keggin-Type
Polyoxometalates to Form an All-Inorganic Octahedral Molecular
Sieve with an Intrinsic 3D Pore System. Inorg. Chem. 2014, 53 (2),
903−911.
AUTHOR INFORMATION
ORCID
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(14) Zhang, Z.; Sadakane, M.; Murayama, T.; Sakaguchi, N.; Ueda,
W. Preparation, Structural Characterization, and Ion-Exchange
Properties of Two New Zeolite-like 3D Frameworks Constructed
by ε-Keggin-Type Polyoxometalates with Binding Metal Ions,
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*
1.5−
2.1−
H11.4[ZnMo O Zn ]
and H [Mn Mo O Mn ] . Inorg.
12
40
2
7.5 0.2 12 40 2
Chem. 2014, 53, 7309−7318.
(15) Zhang, Z.; Sadakane, M.; Noro, S.; Murayama, T.; Kamachi, T.;
Yoshizawa, K.; Ueda, W. Selective Carbon Dioxide Adsorption of ε-
Keggin- Type Zincomolybdate-Based Purely Inorganic 3D Frame-
works. J. Mater. Chem. A 2015, 3, 746−755.
Notes
(16) Zhang, Z.; Ishikawa, S.; Tsuboi, Y.; Sadakane, M.; Murayama,
The authors declare no competing financial interest.
T.; Ueda, W. New Crystalline Complex Metal Oxides Created by
Unit- Synthesis and Their Catalysis Based on Porous and Redox
Properties. Faraday Discuss. 2016, 188, 81−98.
ACKNOWLEDGMENTS
This work was financially supported by the National Natural
Science Foundation of China (Grant 21801141).
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(17) Neumann, R. Activation of Molecular Oxygen, Polyoxometa-
lates, and Liquid-Phase Catalytic Oxidation. Inorg. Chem. 2010, 49,
594−3601.
18) Kim, M.; Chamack, M.; Geletii, Y. V.; Hill, C. L. Synergetic
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(
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