Journal of the American Chemical Society p. 9520 - 9523 (1991)
Update date:2022-08-30
Topics:
Sobkowiak, Andrzej
Sawyer, Donald T.
In acetonitrile the bis(pyridine)cobalt(II) complex [CoII(bpy)2](ClO4)2] activates dioxygen via the reversible formation of a μ-dioxygen complex. This complex dehydrogenates (oxidizes) N-methylanilines, benzyl alcohol, and aldehydes (with subsequent autoxidation). In the absence of substrate, the CoII(bpy)22+ complex reduces dioxygen via residual water in the solvent to generate HOOH. The complex does not activate O2 for reaction with hydrocarbons [even 1,4-cyclohexadiene (ΔHDBE 73 kcal mol-1) is inert].
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