International Journal of Chemical Kinetics p. 539 - 548 (1993)
Update date:2022-08-11
Topics:
Williams
O'RJI
Stone
The relative hydroxyl reaction rate constants from the simulated atmospheric oxidation of selected acetates and other acetates and other esters have been measured. Reactions were carried out at 297 ± 2K in 100-liter FEP teflon-film bags. the OH radicals were generated from the photolysis of methyl nitrite in pure air. Using a rate constant of 2.63 × 10-11 cm3 molecule-1 s-1 for the reaction of OH radicals with propene, principal reference organic compound, the rate constants (×1012 cm3 molecule-1 s-1) obtained for the acetates and esters used in this study. A linear correlation was observed for a plot of the measured relative rate constants vs. the number of CH2 groups per molecule of the following acetates: methyl acetate, ethyl acetate, n-propyl acetate, butyl acetate and pentyl acetate.
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