Page 5 of 7
Journal Name
Journal of Materials Chemistry C
ART82ICLE
DOI: 10.1039/C5TC006 A
fluorescent quantum yield (Φ ) and the BET surface area of a 11 R. Dawson, A. I. Cooper and D. J. Adams, Prog. Polym. Sci., 2012,
FL
series of FLꢀSNWꢀDPPs, which revealed the mechanism of
3
7
, 530.
2 Z. Xiang and D. Cao, Journal of Materials Chemistry A, 2013,
691.
“
Porosity Induced Emission”. (3) Tuning the density of DPP
1
1
1,
moieties in the network could control the color of fluorescence
of FLꢀSNWꢀDPPs, covering a broad range of color from red to
blue. (4) FLꢀSNWꢀDPPꢀ0.11 showed a selective fluorescenceꢀ
off response to TNP quenching and a fluorescenceꢀon response
2
3 Y. Xu, S. Jin, H. Xu, A. Nagai and D. Jiang, Chem. Soc. Rev., 2013,
42, 8012.
to mesitylene. Therefore, the “Porosity Induced Emission” 14 D. Wu, F. Xu, B. Sun, R. Fu, H. He and K. Matyjaszewski, Chem.
approach can be an effective way to design materials with the
solidꢀstate fluorescence. This approach would be extensively
applied for the common dye molecules to be emissive in the
solidꢀstate, which would be further applied as chemical sensors.
Rev., 2012, 112, 3959.
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5 J. W. Colson and W. R. Dichtel, Nat Chem, 2013,
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7 A. Patra and U. Scherf, Chemistry – A European Journal, 2012, 18
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,
,
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1
Acknowledgements
1
The work was supported by the National Basic Research 18 J. Weber and A. Thomas, J. Am. Chem. Soc., 2008, 130, 6334.
Program of China (2013CB733501), the National Nature
Science Foundation of China (No. 91334203, 21376074,
1
2
2
9 Z. Xiang and D. Cao, Macromol. Rapid Commun., 2012, 33, 1184.
0 X. Liu, Y. Xu and D. Jiang, J. Am. Chem. Soc., 2012, 134, 8738.
2
1272069, 20672035), the 111 Project of China (No.B08021)
1 L. Chen, Y. Honsho, S. Seki and D. Jiang, J. Am. Chem. Soc., 2010,
32, 6742.
2 Y. Xu and D. Jiang, Chem. Commun., 2014, 50, 2781.
the Fundamental Research Funds for the Central Universities,
the project of FP7ꢀPEOPLEꢀ2013ꢀIRSES (PIRSESꢀGAꢀ2013ꢀ
1
2
6
12230) and the Key Laboratory of Organofluorine Chemistry,
Shanghai Institute of Organic Chemistry, Chinese Academy of 23 J. Brandt, J. Schmidt, A. Thomas, J. D. Epping and J. Weber,
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Notes and references
4
a
State Key Laboratory of Chemical Engineering and Department of
2
6 Q. Chen, J.ꢀX. Wang, F. Yang, D. Zhou, N. Bian, X.ꢀJ. Zhang, C.ꢀG.
Chemistry, East China University of Science and Technology, Shanghai,
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00237, China.
Yan and B.ꢀH. Han, J. Mater. Chem., 2011, 21, 13554.
E-mail: junhu@ecust.edu.cn; Fax: +86 021 6425 2195; Tel: +86 21
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These authors contributed equally to this work and should be 30 P. Zhang, K. Wu, J. Guo and C. Wang, ACS Macro Lett., 2014, 3,
E-mail: wanglimin@ecust.edu.cn; Fax: +86 021 6425 3881 ; Tel: +86 21
2
6
425 3881
‡
considered coꢀfirst authors.
Electronic supplementary information (ESI) available: For details of
experimental sections, physical properties and chemical sensing
applications of FLꢀSNWꢀDPPs. See DOI:
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