Russian Chemical Bulletin p. 898 - 901 (1997)
Update date:2022-08-11
Topics:
Kazakov
Voloshin
Kabal'nova
Shereshovets
Kazakov
Phosphorescence of methyl acetate formed by isomerization of electron-excited dimethyldioxirane is observed upon excitation at the wavelength of the absorption band of dimethyldioxirane in acetone at 77 K. The quantum yield of the photodecomposition of dimethyldioxirane at 296 K is equal to 13.1?0.7 mol Einstein-1. The high quantum yield of photolysis is evidence for the chain mechanism of decomposition of dimethyldioxirane.
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