Russian Chemical Bulletin p. 1164 - 1166 (1997)
Update date:2022-08-12
Topics:
Dolganova
Dodonov
Zinov'eva
Prezhbog
Di(tert-butylperoxy)triphenylbismuth and the triphenylbismuth - tert-butyl hydroperoxide system react with 2,3-dimethylbutane-2,3-diol, benzopinacol, butane-2,3-diol, and ethane-1,2-diol with the cleavage of the C - C bond of α-glycol to form carbonyl compounds. Both heterolytic (through formation of cyclic triphenylbismuth glycolate) and homolytic cleavage occur.
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