Synthetic Communications p. 1793 - 1800 (1996)
Update date:2022-08-11
Topics:
Guerreiro, Mario Cesar
Schuchardt, Ulf
In the Simmons-Smith reaction, 1,3-dienes are preferentially cyclopropanated at the more electron-rich double bond to afford the trans-vinylcyclopropane; an allylic hydroxyl group increases the reactivity and directs the cyclopropanation to the adjacent double bond.
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