Bulletin of the Chemical Society of Japan p. 215 - 220 (1986)
Update date:2022-08-17
Topics:
Sawada, Hideo
Yoshida, Masato
Hagh, Hidehiko
Aoshima, Kazuyoshi
Kobayashi, Michio
Bis(heptafluorobutyryl) peroxide (1) smoothly reacted with furans and thiophenes under mild conditions to regioselectively give 2-perfluoropropylfurans and thiophenes in high yields.Mechanistically, reactions with furans or thiophenes are considered to be initiated by one-electron transfers from substrates to 1.On the other hand, the perfluoropropylation of pyridine was proceeded by the usual free-radical substitution to a pyridinium salt by a heptafluoropropyl radical produced by the homolytic decomposition of 1.
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