Russian Chemical Bulletin p. 2350 - 2354 (1996)
Update date:2022-08-30
Topics:
Kazakov
Voloshin
Ostakhov
Khusainova
Decomposition of dispiro(diadamantane-l,2-dioxetane) u1, Cd1, Tb1, Pr1, and Ce1 perchlorates was studied by the chemiluminescencc method. The rate constants of decomposition of 1 in complexes of composition 1 Ln"1 and stability constants of these complexes, as well as activation parameters of the decomposition of 1 and thermodynamic parameters of the complexation were determined. A correlation between the thermodynamic parameters of complexation and ionic radii of Ln"1 was found.
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