Journal of Physical Chemistry p. 5633 - 5642 (1993)
Update date:2022-08-17
Topics:
Seakins, Paul W.
Woodbridge, Eric L.
Leone, Stephen R.
The atom-radical reaction Cl + C2H5 -> HCl(υ) + C2H4 is studied using laser flash photolysis, time-resolved Fourier transform infrared emission spectroscopy and broad band infrared chemiluminescence.The Cl atoms and ethyl radicals are produced from a number of different precursors using one or two lasers.The initial HCl vibrational distribution is determined to be HCl (υ=1/2/3/4=0.39+/-0.04/0.29+/-0.03/0.22+/-0.02/0.10+/-0.02).The vibrational distribution is characteristic of an addition-elimination mechanism and can be reproduced using modified statistical theories of energy partitioning within the
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