Journal of the Chemical Society - Faraday Transactions p. 2801 - 2804 (1990)
Update date:2022-08-30
Topics:
Griffiths, William J.
Harris, Frank M.
Parry, David E.
A double-charge-transfer spectroscopy study has provided evidence for the existence of four low-lying electronic states of the CH3I2+ ion, the double-ionization energies to which are 27.0 +/- 0.3, 29.6 +/- 0.3, 31.3 +/- 0.5 and 36.5 +/- 0.5 eV.Three of these energies agree, within experimental error, with those determined previously in a dissociative double photoionization study of CH3I.The present investigation reveals for the first time the state at 29.6 eV.The value of the double-ionization energy to the ground triplet state, calculated in the present investigation using the single-determinant Hartree-Fock approximation to the many-electron wavefunction with corrections of second-order Moeller-Plesset perturbation theory for correlation effects, is 25.80 eV, somewhat lower than the measured value of 27.0 eV.
View MoreTaixing Joxin Bio-tec Co.,Ltd.
website:http://www.joxbio.com
Contact:86-523-87558858 87612088
Address:No.88, chengdong industrial park
CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD
website:http://www.czyys.com
Contact:0086-519-88802789
Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China
Contact:0512-63006287
Address:no.88.YISHENG Road,etdz-WUJIANG,SUZHOU,CHINA
Changsha Huajing Powdery Material Technological Co., Ltd.
Contact:86-731-88879686
Address:Building 2, West Garden, Main Campus of Central South University, Changsha, Hunan Province, China
Daqing E-shine Chemical Co.,LTD
Contact:0086-024-31285112
Address:Hongweiyuan area, Ranghulu district
Doi:10.1039/c5dt04788a
(2016)Doi:10.1021/ja01520a043
(1959)Doi:10.1016/S0040-4039(00)93072-7
(1976)Doi:10.1021/jp020916n
(2002)Doi:10.1039/c39810001267
(1981)Doi:10.1016/0040-4039(90)80156-G
(1990)