Chemical Physics Letters p. 63 - 71 (1995)
Update date:2022-08-16
Topics:
Jodkowski, Jerzy T.
Ratajczak, Emil
Fagerstroem, Kjell
Lund, Anders
Stothard, Nigel D.
et al.
For the title reaction, the pressure dependent rate coefficients were studied at 298 K using two complementary experimental techniques.Pulse radiolysis combined with UV absorption was employed at pressures between 500 and 1000 mbar, while a fast-flow system with a quadrupole mass spectrometer (at low ionization energies) was applied at pressures in the range of 0.7-5.1 mbar.The fall-off curve was constructed in terms of Troe's analysis, and the following high- and low-pressure limiting rate coefficients were derived: krec, infinite = (1.3 +/- 0.3) * 10-10 * T/300)0.42 cm3 molecule-1 s-1 and krec,0
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