Inorganic Chemistry
Article
Hydrogen Peroxide from H2 and O2 Using TiO2-Supported Au−Pd
Catalysts. J. Catal. 2005, 236, 69−79.
(12) Sha, J.; Zheng, E.-J.; Zhou, W.-J.; Liebens, A.; Pera-Titus, M.
Selective Oxidation of Fatty Alcohol Ethoxylates with H2O2 over Au
Catalysts for the Synthesis of Alkyl Ether Carboxylic Acids in Alkaline
Solution. J. Catal. 2016, 337, 199−207.
(30) Majhi, S. M.; Rai, P.; Yu, Y.-T. Facile Approach to Synthesize
Au@ZnO Core−Shell Nanoparticles and Their Application for
Highly Sensitive and Selective Gas Sensors. ACS Appl. Mater.
Interfaces 2015, 7, 9462−9468.
(31) Schladt, T. D.; Shukoor, M. I.; Schneider, K.; Tahir, M. N.;
̈
Natalio, F.; Ament, I.; Becker, J.; Jochum, F. D.; Weber, S.; Kohler,
̈
̈
O.; Theato, P.; Schreiber, L. M.; Sonnichsen, C.; Schroder, H. C.;
(13) Signoretto, M.; Menegazzo, F.; Trevisan, V.; Pinna, F.; Manzoli,
M.; Boccuzzi, F. Investigation on the Stability of Supported Gold
Nanoparticles. Catalysts 2013, 3, 656.
(14) Ferentz, M.; Landau, M. V.; Vidruk, R.; Herskowitz, M. Fixed-
Bed Catalytic Wet Peroxide Oxidation of Phenol with Titania and
Au/Titania Catalysts in Dark. Catal. Today 2015, 241, 63−72.
(15) Li, W.-Z.; Kovarik, L.; Mei, D.; Engelhard, M. H.; Gao, F.; Liu,
J.; Wang, Y.; Peden, C. H. F. A General Mechanism for Stabilizing the
Small Sizes of Precious Metal Nanoparticles on Oxide Supports.
Chem. Mater. 2014, 26, 5475−5481.
(16) Choudhary, T. V.; Goodman, D. W. Oxidation Catalysis by
Supported Gold Nano-Clusters. Top. Catal. 2002, 21, 25−34.
(17) Tian, C.; Zhu, X.; Abney, C. W.; Liu, X.; Foo, G. S.; Wu, Z.; Li,
M.; Meyer, H. M.; Brown, S.; Mahurin, S. M.; Wu, S.; Yang, S.-Z.; Liu,
J.; Dai, S. Toward the Design of a Hierarchical Perovskite Support:
Ultra-Sintering-Resistant Gold Nanocatalysts for CO Oxidation. ACS
Catal. 2017, 7, 3388−3393.
(18) Zhan, W.; He, Q.; Liu, X.; Guo, Y.; Wang, Y.; Wang, L.; Guo,
Y.; Borisevich, A. Y.; Zhang, J.; Lu, G.; Dai, S. A Sacrificial Coating
Strategy toward Enhancement of Metal−Support Interaction for
Ultrastable Au Nanocatalysts. J. Am. Chem. Soc. 2016, 138, 16130−
16139.
Muller, W. E. G.; Tremel, W. Au@MnO Nanoflowers: Hybrid
̈
Nanocomposites for Selective Dual Functionalization and Imaging.
Angew. Chem., Int. Ed. 2010, 49, 3976−3980.
(32) Wang, Z.; Fu, H.; Han, D.; Gu, F. The Effects of Au Species
and Surfactant on the Catalytic Reduction of 4-Nitrophenol by Au@
SiO2. J. Mater. Chem. A 2014, 2, 20374−20381.
(33) Sun, H.; He, J.; Wang, J.; Zhang, S.-Y.; Liu, C.; Sritharan, T.;
Mhaisalkar, S.; Han, M.-Y.; Wang, D.; Chen, H. Investigating the
Multiple Roles of Polyvinylpyrrolidone for a General Methodology of
Oxide Encapsulation. J. Am. Chem. Soc. 2013, 135, 9099−9110.
(34) Abis, L.; Freakley, S. J.; Dodekatos, G.; Morgan, D. J.; Sankar,
M.; Dimitratos, N.; He, Q.; Kiely, C. J.; Hutchings, G. J. Highly Active
Gold and Gold−Palladium Catalysts Prepared by Colloidal Methods
in the Absence of Polymer Stabilizers. ChemCatChem 2017, 9, 2914−
2918.
(35) Lin, F.-h.; Doong, R.-a. Catalytic Nanoreactors of Au@Fe3O4
Yolk−Shell Nanostructures with Various Au Sizes for Efficient
Nitroarene Reduction. J. Phys. Chem. C 2017, 121, 7844−7853.
(36) Haruta, M. Gold as a Novel Catalyst in the 21st Century:
Preparation, Working Mechanism and Applications. Gold Bull. 2004,
37, 27−36.
(37) Cao, S.; Tao, F.; Tang, Y.; Li, Y.; Yu, J. Size- and Shape-
Dependent Catalytic Performances of Oxidation and Reduction
Reactions on Nanocatalysts. Chem. Soc. Rev. 2016, 45, 4747−4765.
(38) Campbell, C. T. The Energetics of Supported Metal
Nanoparticles: Relationships to Sintering Rates and Catalytic Activity.
Acc. Chem. Res. 2013, 46, 1712−1719.
(39) Turner, M.; Golovko, V. B.; Vaughan, O. P. H.; Abdulkin, P.;
Berenguer-Murcia, A.; Tikhov, M. S.; Johnson, B. F. G.; Lambert, R.
M. Selective Oxidation with Dioxygen by Gold Nanoparticle Catalysts
Derived from 55-Atom Clusters. Nature 2008, 454, 981−983.
(40) Yamazoe, S.; Koyasu, K.; Tsukuda, T. Nonscalable Oxidation
Catalysis of Gold Clusters. Acc. Chem. Res. 2014, 47, 816−824.
(41) Imura, Y.; Koizumi, S.; Akiyama, R.; Morita-Imura, C.; Kawai,
T. Highly Stable Silica-Coated Gold Nanoflowers Supported on
Alumina. Langmuir 2017, 33, 4313−4318.
(42) Pan, X.; Yi, Z. Graphene Oxide Regulated Tin Oxide
Nanostructures: Engineering Composition, Morphology, Band
Structure, and Photocatalytic Properties. ACS Appl. Mater. Interfaces
2015, 7, 27167−27175.
(43) Yan, Z.; Chinta, S.; Mohamed, A. A.; Fackler, J. P.; Goodman,
D. W. The Role of F-Centers in Catalysis by Au Supported on MgO.
J. Am. Chem. Soc. 2005, 127, 1604−1605.
(44) Lin, F.-h.; Doong, R.-a. Bifunctional Au−Fe3O4 Hetero-
structures for Magnetically Recyclable Catalysis of Nitrophenol
Reduction. J. Phys. Chem. C 2011, 115, 6591−6598.
(45) Wunder, S.; Polzer, F.; Lu, Y.; Mei, Y.; Ballauff, M. Kinetic
Analysis of Catalytic Reduction of 4-Nitrophenol by Metallic
Nanoparticles Immobilized in Spherical Polyelectrolyte Brushes. J.
Phys. Chem. C 2010, 114, 8814−8820.
(46) Pan, X.; Gao, X.; Chen, X.; Lee, H. N.; Liu, Y.; Withers, R. L.;
Yi, Z. Design Synthesis of Nitrogen-Doped TiO2@Carbon Nano-
sheets toward Selective Nitroaromatics Reduction under Mild
Conditions. ACS Catal. 2017, 7, 6991−6998.
(47) Liang, S.; Wu, L.; Bi, J.; Wang, W.; Gao, J.; Li, Z.; Fu, X. A
Novel Solution-Phase Approach to Nanocrystalline Niobates:
Selective Syntheses of Sr0.4H1.2Nb2O6 Nanopolyhedrons and
SrNb2O6 Nanorods Photocatalysts. Chem. Commun. 2010, 46,
1446−1448.
(48) Zhou, Y.; Zhang, Y.; Lin, M.; Long, J.; Zhang, Z.; Lin, H.; Wu,
J. C. S.; Wang, X. Monolayered Bi2WO6 Nanosheets Mimicking
Heterojunction Interface with Open. Nat. Commun. 2015, 6, 8340.
(19) Li, G.; Tang, Z. Noble Metal Nanoparticle@Metal Oxide
Core/Yolk-Shell Nanostructures as Catalysts: Recent Progress and
Perspective. Nanoscale 2014, 6, 3995−4011.
(20) Qi, J.; Chen, J.; Li, G.; Li, S.; Gao, Y.; Tang, Z. Facile Synthesis
of Core-Shell Au@CeO2 Nanocomposites with Remarkably En-
hanced Catalytic Activity for CO Oxidation. Energy Environ. Sci. 2012,
5, 8937−8941.
(21) Yu, K.; Wu, Z.; Zhao, Q.; Li, B.; Xie, Y. High-Temperature-
Stable Au@SnO2 Core/Shell Supported Catalyst for CO Oxidation. J.
Phys. Chem. C 2008, 112, 2244−2247.
(22) Kuo, C.-H.; Hua, T.-E.; Huang, M. H. Au Nanocrystal-Directed
Growth of Au−Cu2O Core−Shell Heterostructures with Precise
Morphological Control. J. Am. Chem. Soc. 2009, 131, 17871−17878.
(23) Zhang, L.; Blom, D. A.; Wang, H. Au−Cu2O Core−Shell
Nanoparticles: A Hybrid Metal-Semiconductor Heteronanostructure
with Geometrically Tunable Optical Properties. Chem. Mater. 2011,
23, 4587−4598.
(24) Liu, D.-Y.; Ding, S.-Y.; Lin, H.-X.; Liu, B.-J.; Ye, Z.-Z.; Fan, F.-
R.; Ren, B.; Tian, Z.-Q. Distinctive Enhanced and Tunable Plasmon
Resonant Absorption from Controllable Au@Cu2O Nanoparticles:
Experimental and Theoretical Modeling. J. Phys. Chem. C 2012, 116,
4477−4483.
(25) Kuo, C.-H.; Yang, Y.-C.; Gwo, S.; Huang, M. H. Facet-
Dependent and Au Nanocrystal-Enhanced Electrical and Photo-
catalytic Properties of Au−Cu2O Core−Shell Heterostructures. J. Am.
Chem. Soc. 2011, 133, 1052−1057.
(26) Lekeufack, D. D.; Brioude, A.; Mouti, A.; Alauzun, J. G.;
Stadelmann, P.; Coleman, A. W.; Miele, P. Core-Shell Au@(TiO2,
SiO2) Nanoparticles with Tunable Morphology. Chem. Commun.
2010, 46, 4544−4546.
(27) Seh, Z. W.; Liu, S.; Zhang, S.-Y.; Shah, K. W.; Han, M.-Y.
Synthesis and Multiple Reuse of Eccentric Au@TiO2 Nanostructures
as Catalysts. Chem. Commun. 2011, 47, 6689−6691.
(28) Wu, X.-F.; Song, H.-Y.; Yoon, J.-M.; Yu, Y.-T.; Chen, Y.-F.
Synthesis of Core−Shell Au@TiO2 Nanoparticles with Truncated
Wedge-Shaped Morphology and Their Photocatalytic Properties.
Langmuir 2009, 25, 6438−6447.
(29) Zhang, N.; Liu, S.; Fu, X.; Xu, Y.-J. Synthesis of M@TiO2 (M =
Au, Pd, Pt) Core−Shell Nanocomposites with Tunable Photo-
reactivity. J. Phys. Chem. C 2011, 115, 9136−9145.
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