Tetrahedron Letters p. 7059 - 7062 (1997)
Update date:2022-08-28
Topics:
Behnke, Dirk
Hamm, Stefan
Hennig, Lothar
Welzel, Peter
InCl3-mediated coupling of δ-alkoxy allylic stannane 9b with aldehydes has been shown to give the α-coupling products in high yield, probably via two S(E)' processes. Most specifically, drimenal (rac-l) has been converted into labdane derivative 17 which is considered to be an important intermediate on the way to forskolin.
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