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bromination of unsaturated C-C bonds, is facile and
quantitative, and the subsequent changes in hybridization
significantly impact the elastic moduli of the MOFs. The
usefulness of PSM to introduce sp3 hybridised carbons into
otherwise rigid MOFs is further demonstrated by the fact that
we have been unable as yet to prepare an isoreticular
zirconium MOF using the analogous -CH2CH2- bridged ligand,
4,4′-ethane-1,2-diyldibenzoic acid (see SI, Section S7),
presumably as a result of its conformational freedom. We
anticipate that ligand functionalisation will be a powerful tool
to modulate mechanical compliance of MOFs in the future.
DOI: 10.1039/C5DT03178H
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RSF thanks the Royal Society for receipt of a University
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acknowledge pump-priming funding from the EPSRC Directed
Assembly Network (PP 14 05 03). TDB thanks Trinity Hall
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Notes and references
‡The chemical structures of all ligands and their abbreviation
scheme used in this study are given in the Supporting
Information, in Scheme S1.
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§The increase in mass of the brominated MOFs is not sufficient
to induce the drastic decreases in gravimetric BET surface areas
3
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