Tetrahedron Letters p. 3155 - 3158 (1993)
Update date:2022-08-16
Topics:
Cotterill
Gill
The anthraquinones (S)-(-)-austrocorticin (9) and (S)-(+)-dermolactone (2) are synthesised using the chiral dienes 6a and 6b, respectively; comparison with these synthetic compounds establishes that natural austrocorticin has the (R) absolute configuration while dermolactone occurs naturally as a mixture of enantiomers in which the (S) isomer predominates.
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(1968)Doi:10.1021/ja512053t
(2015)Doi:10.1021/ja01185a032
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(1998)Doi:10.1021/jo01076a611
(1960)
