Journal of Organometallic Chemistry p. 31 - 38 (1985)
Update date:2022-08-11
Topics:
Nagendrappa, Gopalpur
Vidyapati, T. J.
Acid-catalysed hydrolysis of epoxysilanes derived from common-, medium- and large-ring vinylsilanes is described.Whereas the large epoxysilanes give ketones, the medium-ring epoxysilanes give transannular products and the common-ring epoxysilanes provide α,β-dihydroxysilanes.The results are explained as due to the conformational rigidity in the common-ring silyldiols and the conformational freedom in the large-ring silyldiols to achive antiperiplanar geometry for 1,2-elimination of trimethylsilanol.
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