Russian Chemical Bulletin p. 967 - 974 (1997)
Update date:2022-08-25
Topics:
Gromov
Fedorova
Vedernikov
Fedorov
Alfimov
Novel styryl dyes containing dithia-15(18)-crown-6(5)-ether moieties were synthesized. Their selective complex formation with Hg2+ and Ag+ ions was studied by 1H NMR and electronic spectroscopy; the stability constants of the Ag+ complexes and the relative stability constants (in relation to benzodithia-18-crown-6) of the Hg2+ complexes were determined. The chemical shifts of the β,β′-protons in the CH2S group change upon the complex formation in parallel with the logK1 values of the complexes.
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