Phosphorus, Sulfur and Silicon and the Related Elements p. 41 - 59 (1998)
Update date:2022-08-29
Topics:
Len, Christophe
Postel, Denis
Ronco, Gino
Villa, Pierre
Regiospecific carbamoylation of O-isopropylidene protected monosaccharides and itols gave a large range of novel carbamoyl, thiocarbamoyl and dithiocarbamoyl esters. These fully, partially and unprotected carbohydrates possess both modulable hydrophilic character and potential biological properties. Some carbamoyl esters showed, by NMR spectroscopy, characteristics of Z-E isomerism; the rotational energy barrier was higher for the thiocarbamates than for the corresponding carbamates.
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