Journal of Molecular Structure p. 23 - 27 (2003)
Update date:2022-08-11
Topics:
Xu, Jing-Yuan
Gu, Wen
Li, Ling
Yan, Shi-Ping
Cheng, Peng
Liao, Dai-Zheng
Jiang, Zong-Hui
A new nickel(II) complex, [NiL2]Cl2 (L = N,N-bis(benzimidazol-2-yl-methyl)amine), was synthesized and its crystal structure was determined. According to X-ray crystallographic studies, each nickel(II) ion was six-coordinated with six nitrogen atoms of two L ligands. The complex crystallizes in triclinic system, space group P1?, a = 9.764(3) ?, b = 11.032(3) ?, c = 16.402(5) ?, α = 80.529(6)°, β = 79.180(7)°, γ = 74.232(6)°, and Z = 2. The title complex forms two-dimensional hydrogen bond network structures between the chlorine atoms and the nitrogens of L. The IR and UV spectroscopy were measured. The absorption bands of d-d electron transition are assigned, the values of Dq and B were calculated according to the electronic spectrum of the complex.
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